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σ-Bond insertion reactions of two strained diradicaloids

https://doi.org/10.1038/s41586-025-08745-1

Tena_Meza, Arismel; Rivera, Christina A; Shao, Huiling; Kelleghan, Andrew V; Houk, K N; Garg, Neil K (April 2025, Nature)

Free, publicly-accessible full text available April 17, 2026
Facile synthesis of 2-aza-9,10-diphenylanthracene and the effect of precise nitrogen atom incorporation on OLED emitters performance

https://doi.org/10.1039/d3ma00280b

Darzi, Evan R; Stanfield, Dane A; McDermott, Luca; Kelleghan, Andrew V; Schwartz, Benjamin J; Garg, Neil K (July 2023, Materials Advances)

We report a comparative study of the well-known fluorophore 9,10-diphenylanthracene with a synthetic aza analog. OLED devices were prepared and showed that nitrogen atom incorporation leads to an unexpected red shift in electroluminescence.
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Intercepting fleeting cyclic allenes with asymmetric nickel catalysis

https://doi.org/10.1038/s41586-020-2701-2

Yamano, Michael M.; Kelleghan, Andrew V.; Shao, Qianzhen; Giroud, Maude; Simmons, Bryan J.; Li, Bo; Chen, Shuming; Houk, K. N.; Garg, Neil K. (October 2020, Nature)
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